TRIS(DIBENZYLIDECETONE)DIPALLADIUM(O)CHLOROFORM
CAS No :
52522-40-4
Product Code :
AMC804
Chemical Formula :
Pd2(dba)3CHCl3
Formula Weight :
1035.1
Metal Content :
20.3%
Appearance :
Dark Purple or Dark Brown crystalline Powder
Product Usage : Tris(dibenzylidecetone)dipalladium(o)Chloroform is used to compose the catalytic system for the preparation of homoallylpalladium complexes.These complexes underwent in situ Stille type cross coupling with various vinyltin reagents to afford the cyclized products bearing allyl appendages. It is also used as palladium source in the asymmetric transformations of 3,4-epoxy-1-butene. Tris(dibenzylidecetone)dipalladium(o)Chloroform acts as a catalyst for the Heck cross-coupling reaction of iodobenzene with styrene, cyclization, [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes etc.
This Product is also known as :
Dipalladiumtris(dibenzylideneacetone) chloroform adduct,
Dipalladiumtris(dibenzylideneacetone) chloroform complex,
Tris(dibenzylideneacetone)dipalladium-chloroform adduct,
Tris DBA chloroform adduct,
etc